The Devil Wears Prada star — who cut a stylish figure in a satin suit at the Versace Icons dinner the day before — donned a pair of chrome pointed-toe heels with bows.

She was also seen toting around a small silver shoulder bag as she posed for photos before heading into the event at The New York Public Library.

Ethereal: Anne Hathaway looked captivating at the Clooney Foundation For Justice’s second annual Albie Awards in New York City on Thursday, where she wore a slip dress with a light green and silver checkered pattern

The Princess Diaries alumna wore dainty silver earrings as well as a delicate pendant necklace.

To jazz up her look, she was bejeweled in various chunky tennis bracelets and silver statement rings.

The Golden Globe winner fashioned her dark brunette tresses in a voluminous half-up and half-down hairstyle for to complete her elegant look.

She also rocked a sultry makeup look to highlight her radiant skin and sharp features.

As she posed for pictures, she smoldered in a brown smoky eyeshadow look teamed with pearlescent pink blush and a rosy pout.

This event comes about a week before her romantic comedy film, She Came To Me, is released in theaters.

In the flick, she stars alongside Game of Thrones vet Peter Dinklage, 54, as the two play an atypical married couple navigating a rocky phase in their marriage.

The brunette beauty — who is known for her ever-youthful visage and was recently named as the ambassador of Shiseido‘s Vital Protection line — plays his wife and former therapist, Patricia.

Silver screen star: At the star-studded affair held to honor ‘defenders of justice’, she dressed to the nines and teamed her gown with matching silver accessories

Brunette beauty: The Golden Globe winner fashioned her dark brunette tresses in a voluminous half-up and half-down hairstyle for to complete her elegant look

According to the synopsis, the amusing flick follows Steven Lauddem (Dinklage) as he struggles with a creative block and is unable to come up with another masterpiece for his highly-anticipated comeback to the opera.

His wife, Patricia, encourages him to seek inspiration. After taking her advice, he ends up rediscovers his passion after an unexpected one-night stand.

He encounters a free-spirited tugboat captain and goes on ‘an unpredictable voyage into uncharted waters’ with her.

She Came To Me — written and directed by Rebecca Miller — is set to premiere in theaters on October 6.